Advantages of Mortar Incorporating Redispersible Latex Powder
Release Time:
2020-03-09
Source:
In mortar, polymers serve as a secondary binder that complements the inorganic cement binder. The dual cement–redispersible polymer powder system leverages the respective advantages of each constituent, resulting in excellent synergy and complementary performance that enhances the mortar’s bond strength.
Mortar incorporating redispersible polymer powder exhibits the following advantages:
1. Exhibits excellent adhesion to various substrates.
In mortar, polymers serve as a secondary binder that complements the inorganic cement binder. The two cementitious systems—cement and redispersible polymer powder—each leverage their respective advantages, resulting in excellent synergy in mortar performance and thereby enhancing its bond strength. The improvement in the bonding performance of mortar attributable to redispersible polymer powder can be attributed to the following factors:
① The polymer forms a polymer film with high adhesion between the cement paste and the aggregate, while simultaneously sealing the pores within the mortar. Cement hydration and polymer film formation occur concurrently, ultimately resulting in an interpenetrating network structure in which the cement paste and the polymer film are intricately intertwined.
② Polymers with reactive functional groups may undergo chemical reactions with silicates on the surface of solid calcium hydroxide, thereby enhancing the bond between cement hydration products and aggregates and improving the bonding performance of mortars to various substrates.
③ The weakest link in mortar is the interface between the mortar and the cement paste, which constitutes the transition zone. This zone is a critical region where shrinkage cracks initiate and bond strength is lost; under stress, cracks are most likely to nucleate at this interface. Incorporating redispersible polymer powder into the mortar results in the formation of a polymer film on the surface of the mortar particles, which acts as a bridging layer between the mortar and the substrate. This reduces microcracking at the mortar–cement-paste interface, promotes the healing of shrinkage cracks, and thereby enhances the bond strength of the mortar. Moreover, the tensile strength of the polymer film is more than ten times that of ordinary mortar.
2. Ensure good water retention of the fresh mortar
The hydration of cement is a relatively slow process; if cement is not in prolonged contact with water, hydration will cease, thereby impairing the development of later-age strength. John Schultz simulated typical summer conditions on a west-facing wall by applying a 10-mm-thick dry-mix repair mortar over a concrete slab. The tests showed that the unmodified mortar failed, whereas the polymer-modified mortar exhibited higher strength than that achieved under standard 28-day curing conditions. This is attributed to the polymer powder’s enhanced water-retention capability, which promotes increased late-age strength, as well as the formation of fine polymer phases within the mortar, which improve bond strength.
3. Improving the Workability of Fresh Mortar
After incorporating redispersible latex powder into dry-mix mortar, the workability of the mortar is significantly improved, primarily due to the following factors:
① When redispersible latex powder is mixed with mortar, the particles of the powder are coated with a water-soluble protective colloid. This coating prevents irreversible agglomeration among the polymer particles, thereby imparting a lubricating effect that enables the particles to disperse uniformly within the cement paste. These well-dispersed particles act like “ball bearings,” allowing the individual constituents of the mortar to flow independently and thus improving the workability of the mortar.
② Redispersible latex powder itself possesses a certain air-entraining effect; this air-entraining effect imparts compressibility to the mortar, resulting in excellent workability. In addition, the presence of fine air bubbles acts like rolling bearings within the mix, further enhancing its workability.
4 Redispersible Latex Powder Improves the Flexibility and Crack Resistance of Mortar
After the addition of redispersible latex powder to mortar, both the flexural-to-compressive strength ratio and the tensile-to-compressive strength ratio are significantly improved, indicating a substantial reduction in brittleness and a marked enhancement in toughness, thereby improving the crack resistance of the mortar. Upon dehydration and film formation in the mortar, the redispersible latex powder not only fills defects and pores within the cement paste but also promotes interfacial bonding among cement hydration products and between the aggregate particles, forming an interpenetrating polymer network. Given that the elastic modulus of the polymer film is lower than that of the mortar, the overall brittleness of the mortar is reduced. The increased flexibility of the mortar raises its ultimate deformation capacity at failure, enabling it to absorb maximum energy required for the propagation of defects and microcracks and thus to withstand higher stresses before failure. Moreover, the polymer film exhibits a self-stretching mechanism; within the rigid skeletal structure formed in the hardened mortar, it functions as a compliant joint, thereby maintaining the elasticity and toughness of the rigid framework. Some portions of the polymer film formed on the surface of mortar particles contain micropores, which are subsequently filled by the surrounding mortar matrix, reducing stress concentrations and allowing for relaxation under external loading without causing catastrophic failure. The presence of highly flexible and highly elastic polymer regions further enhances the mortar’s flexibility and resilience.
5. Improved the wear resistance and impermeability of the mortar.
Latex powder exhibits a certain air-entraining effect; however, when added in large quantities, it can lead to excessive air entrainment in the mortar, causing small air bubbles to coalesce into larger ones that eventually escape from the mortar matrix, thereby reducing the mortar’s air content. Consequently, as the dosage of latex powder increases, the dry apparent density of the mortar also increases. Moreover, modified mortars demonstrate improved wear resistance and impermeability. Wear resistance is particularly critical for floor applications and constitutes a key performance characteristic of self-leveling floor coatings.